Hexafluorobutadiene

Hexafluoro-1,3-butadiene (C₄F₆) is a critical gas that defines the performance of etching processes in advanced semiconductor manufacturing. Its purity level directly determines the yield and device performance of cutting-edge chip fabrication. Leveraging continuous process innovation, Jinhong Gas has achieved simultaneous breakthroughs in both purity and mass production capacity of C₄F₆, establishing itself as an indispensable high-purity gas supplier for supporting advanced semiconductor processes.

Process

In semiconductor manufacturing, hexafluorobutadiene (C4F6) is a critical etching gas widely applied in the following scenarios: Precision dry etching of materials such as silicon and silicon nitride in the production of advanced logic chips and high-end memory devices (e.g., 3D NAND). With its high selectivity and excellent profile control, it is particularly suitable for fine-pattern etching processes at 65 nm technology nodes and below. The industrial synthesis of hexafluorobutadiene (C4F6) primarily adopts a catalytic fluorination process, in which hydrogen fluoride reacts with specific halogenated butenes or butynes. It can also be produced via reduction or fluorine-exchange pathways from hexafluorobutadiene derivatives. At Jinhong Gas, multi-stage purification and precision rectification technologies are employed to deeply refine crude products. The core lies in the effective removal of trace isomers, reactive impurities, and metal ions, ensuring the product meets electronic-grade purity requirements. Currently, Jinhong Gas has achieved an annual production capacity of 200 tons of high-purity (≥99.99%) hexafluorobutadiene.
GAS Hexafluorobutadiene
CAS No. 685-63-2
Purity of C4F6 ≥99.99%
O2+Ar <1 ppm
N2 <5 ppm
CO2 <2 ppm
Other fluorocarbons <100 ppm
Isopropyl alcohol(C3H8O) < 2 ppm
Water <5 ppm
Acidity (in HF) <2 ppm
Total impurities <100 ppm

Applications

Semiconductors

High-purity hexafluorobutadiene (≥4N) is primarily used in dry etching processes in advanced semiconductor manufacturing. It serves as a high-quality etching gas for key materials such as silicon nitride and polysilicon in the production of high-end logic chips, 3D NAND memory, and DRAM, enabling low-damage etching of silicon dioxide with high selectivity.

Industrial Applications

In the industrial sector, hexafluorobutadiene can be used as an intermediate or raw material in certain fluorination reactions, supporting the synthesis of high-value fluorinated fine chemicals.

Scientific Research

In research, high-purity hexafluorobutadiene is used as a reference material or process gas for studies on new etching chemistries, novel material development, and related analytical testing.

Frequently Asked Question

What product specifications can you provide?

Cylinder: DOT 47L Valve: DISS 724 Filling weight: 45 kg

How is hexafluorobutadiene (C₄F₆) produced?

Industrial production typically uses halogenated C4 hydrocarbons as raw materials, which react with hydrogen fluoride in the presence of specific catalysts via gas-phase or liquid-phase fluorination to generate crude products. These are then refined through a series of complex chemical purification and physical rectification processes to produce high-purity electronic-grade C₄F₆

Is hexafluorobutadiene environmentally friendly?

Compared with traditional perfluorocarbon (PFC) etching gases, hexafluorobutadiene has a significantly lower global warming potential (GWP), making it more environmentally friendly. It is one of the green alternative gases that the semiconductor industry is actively adopting to reduce carbon footprint.

What are the advantages of hexafluorobutadiene in etching processes?

Compared with conventional gases like carbon tetrafluoride, hexafluorobutadiene provides higher etching selectivity and better anisotropic profile control, helping to better protect underlying materials during etching and enabling the fabrication of finer and more reliable circuit structures.

What precautions should be taken when using hexafluorobutadiene?

Although its toxicity is relatively low, it remains a high-pressure liquefied gas. It must be used in well-ventilated areas, away from heat and open flames. Operators should wear appropriate personal protective equipment (PPE) and strictly follow the guidance provided in the Safety Data Sheet (SDS).

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